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Monday, June 14, 2010
Breeder Reactors
The fast breeder or fast breeder reactor (FBR) is a fast neutron reactor designed to breed fuel by producing more fissile material than it consumes. The FBR is one possible type of breeder reactor.
The reactors are used in nuclear power plants to produce nuclear power and nuclear fuel.
FBRs usually use a mixed oxide fuel core of up to 20% plutonium dioxide (PuO2) and at least 80% uranium dioxide (UO2). Another fuel option is metal alloys, typically a blend of uranium, plutonium, and zirconium. The plutonium used can be supplied by reprocessing reactor outputs or "off the shelf" from dismantled nuclear weapons.
In many FBR designs, the reactor core is surrounded in a blanket of tubes containing non-fissile uranium-238 which, by capturing fast neutrons from the reaction in the core, is partially converted to fissile plutonium-239 (as is some of the uranium in the core), which can then be reprocessed for use as nuclear fuel. Other FBR designs rely on the geometry of the fuel itself (which also contains uranium-238) to attain sufficient fast neutron capture.
The ratio between the Pu239 (or U235) fission cross-section and the U238 absorption cross-section is much higher in a thermal spectrum than in a fast spectrum. Therefore a higher enrichment of the fuel is needed in a fast reactor in order to reach a self-sustaining nuclear chain reaction.
Since a fast reactor uses a fast spectrum, no moderator is required to thermalize the fast neutrons.
All current fast reactor designs use liquid metal as the primary coolant, to transfer heat from the core to steam used to power the electricity generating turbines. Some early FBRs used mercury, and other experimental reactors have used NaK. Both of these choices have the advantage that they are liquids at room temperature, which is convenient for experimental rigs but less important for pilot or full scale power stations.
Sodium is the normal coolant for large power stations, but lead has been used successfully for smaller generating rigs. Both coolant choices are being studied as possible Generation IV reactors, and each presents some advantages.A gas-cooled option is also being studied, although no gas-cooled fast reactor has reached criticality.
Liquid water is an undesirable primary coolant for fast reactors because large amounts of water in the core are required to cool the reactor. Since water is a neutron moderator, this slows neutrons to thermal levels and prevents the breeding of uranium-238 into plutonium-239. Theoretical work has been done on reduced moderation water reactors, which may have a sufficiently fast spectrum to provide a breeding ratio slightly over 1. This would likely result in an unacceptable power derating and high costs in an LWR-derivative reactor, but the supercritical water coolant of the SCWR has sufficient heat capacity to allow adequate cooling with less water, making a fast-spectrum water cooled reactor a practical possibility. In addition, a heavy water moderated thermal breeder reactor, using thorium to produce uranium-233, is theoretically possible (see Advanced Heavy Water Reactor).
Under appropriate operating conditions, the neutrons given off by fission reactions can "breed" more fuel from otherwise non-fissionable isotopes. The most common breeding reaction is that of plutonium-239 from non-fissionable uranium-238. The term "fast breeder" refers to the types of configurations which can actually produce more fissionable fuel than they use, such as the LMFBR. This scenario is possible because the non-fissionable uranium-238 is 140 times more abundant than the fissionable U-235 and can be efficiently converted into Pu-239 by the neutrons from a fission chain reaction.
France has made the largest implementation of breeder reactors with its large Super-Phenix reactor and an intermediate scale reactor (BN-600) on the Caspian Sea for electric power and desalinization.
In the breeding of plutonium fuel in breeder reactors, an important concept is the breeding ratio, the amount of fissile plutonium-239 produced compared to the amount of fissionable fuel (like U-235) used to produced it. In the liquid-metal, fast-breeder reactor (LMFBR), the target breeding ratio is 1.4 but the results achieved have been about 1.2 . This is based on 2.4 neutrons produced per U-235 fission, with one neutron used to sustain the reaction.
The time required for a breeder reactor to produce enough material to fuel a second reactor is called its doubling time, and present design plans target about ten years as a doubling time. A reactor could use the heat of the reaction to produce energy for 10 years, and at the end of that time have enough fuel to fuel another reactor for 10 years.
Several countries are developing more proliferation resistant reprocessing methods that don't separate the plutonium from the other actinides. For instance, the pyrometallurgical process when used to reprocess fuel from the Integral Fast Reactor leaves large amounts of radioactive actinides in the reactor fuel. Removing these transuranics in a conventional reprocessing plant would be extremely difficult as many of the actinides emit strong neutron radiation, requiring all handling of the material to be done remotely, thus preventing the plutonium from being used for bombs while still being usable as reactor fuel.
Thorium fueled reactors may pose a slightly higher proliferation risk than uranium based reactors. The reason for this is that while Pu-239 will fairly often fail to undergo fission on neutron capture, producing Pu-240, the corresponding process in the thorium cycle is relatively rare. Thorium-232 converts to U-233, which will almost always undergo fission successfully, meaning that there will be very little U-234 produced in the reactor's thorium/U-233 breeder blanket, and the resulting pure U-233 will be comparatively easy to extract and use for weapons. However, U-233 is normally accompanied by U-232 (produced in neutron knock-off reactions), which has the strong gamma emitter Tl-208 in its decay chain. These gamma rays complicate the safe handling of a weapon and the design of its electronics, which is why U-233 has never been pursued for weapons beyond proof-of-concept demonstrations. One proposed solution to this is to mix natural or depleted uranium into the thorium breeder blanket. When diluted with enough U-238, the resulting uranium mixture would no longer be weapons usable, but significant quantities of plutonium would also be produced.
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